Metamorphism
- Changes in Rock Composition or Texture
- Due to Heat, Pressure and Action of Fluids
Where Does the Heat Come from?
- Uranium and Thorium to Other Elements + Lead + Radiation
- Potassium-40 to Calcium-40 or Argon-40 + Radiation
Where Does the Pressure Come from?
- Air Pressure = 14 P.s.i. (1 Atmosphere or 1 Bar = 100,000 pascals)
- Pressure Beneath 10 Meters (33 Ft.) Of Water = 1 Atm. = 1 Bar.
- Same Pressure Beneath 3.5 M (10 Ft.) Of Rock
- Pressure in Deepest Part of Ocean = 1000 Bar.
- Pressure under One Mile of Rock = 500 Bar.
1000 Bars (2 Mi. or 3 km Of Rock) = 1 Kilobar (Kb.)
Metamorphic Rocks Form Many Km below the Surface
How Do They Get to the Surface?
- Tectonic Uplift & Erosion
- Isostasy & Erosion
Types of Metamorphism
Contact
- Around Intrusions
- Shallow: 0-6 Km
- Low Pressure
- Local
Regional
- Wide Areas
- 5-20 Km, Sometimes 30+
- High Pressure
- Usually Accompained by Deformation
What Happens During Metamorphism
Minerals React to Form New Minerals
- 2SiO2 + CaMg(CO3)2 == CaMgSi2O6 + 2CO2
- Quartz + Dolomite == Pyroxene
Minerals Change Form
- Al2SiO5 == Al2SiO5
- Andalusite == Kyanite
New Materials Are Added (Metasomatism)
- CaMg(SiO3)2 + 2CO2 == CaMg(CO3)2 + 2SiO2
- Pyroxene + CO2 == Dolomite + Quartz
- Minerals in Solution == Ore Bodies
Recrystallization
Why Don't Rocks "De-metamorphose"?
- Reactions Can't Reverse Because Ingredients Lost
- 2AlSi2O5(OH) == Al2SiO5 + 3SiO2 + H2O
- Clay Mineral == Andalusite + Quartz + Water (Lost)
- An example of carbonate metamorphism:
- CaMg(CO3)2 + 2SiO2 == CaMgSi2O6 +2CO2
- Dolomite + Quartz == Pyroxene + CO2 (Lost)
- Reactions "Freeze"
- Sometimes it Does Happen
- Retrograde Metamorphism
Grade - Degree to Which the Rock Has Changed Composition
- Can Often See Original Bedding
- Can Sometimes Even See Deformed Fossils
- At High Grades, Rocks Can Often Lose All Trace of Their Original Appearance
Major Metamorphic Rock Types
Temp C | Temp F | Coal | Limestone | Sandstone | Basalt | Shale | Index Minerals |
---|---|---|---|---|---|---|---|
Lignite Bituminous | |||||||
500 | Anthracite | ||||||
300 | 600 | Graphite | Marble | Slate | Chlorite | ||
700 | Quartzite | ||||||
800 | Greenstone | Phyllite | Biotite | ||||
500 | 900 | Schist | Garnet | ||||
1000 | Amphibolite | Staurolite | |||||
600 | 1100 | Gneiss | Kyanite | ||||
1200 | Sillimanite | ||||||
700 | Melting Begins |
Polymorphism
- Al2SiO5
- Kyanite
- Sillimanite
- Andalusite
- Ice - 6 high pressure forms
- Diamond - Graphite
- Calcite - Aragonite
- Quartz -
- - Tridymite - Cristobalite (increasing temperature)
- - Coesite - Stishovite (increasing pressure)
Metamorphic Facies
Not all changes in rocks are metamorphism:
- Surface temperature and pressure --- Weathering
- Sedimentary rocks, surface to 250 C --- Diagenesis
Depth\Temp | 300 C | 400 C | 500 C | 600 C | 700 C | 800 C |
---|---|---|---|---|---|---|
5 km | Zeolite | Contact Metamorphism - Andalusite forms | ||||
10 km - 3 kb | Greenschist Chlorite, Biotite form
| Amphibolite Garnet, Staurolite, Kyanite form
| Granulite Sillimanite forms Muscovite breaks down to K-feldspar Partial Melting
| |||
15 km | Blueschist | |||||
20 km - 6 kb | ||||||
25 km | ||||||
30 km - 9 kb | ||||||
35 km | ||||||
40 km - 12 kb | Eclogite (Mantle) |
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